| Are the following reactions predicted to have an equilibrium constant K greater or less than one based on HSAB theory? Unless otherwise stated, assume gas-phase or hydrocarbon solution (i.e., not aqueous) and 25 °ree;C. |
| 1. |
| HgI + LiF |
 |
HgF + LiI |
|
[Solution] |
| 2. |
| TlH + Na+ |
 |
Tl+ + NaH |
|
[Solution] |
| 3. |
| Cu(SOMe2) |
 |
Cu(OSMe2) |
|
[Solution] |
| 4. |
| [Fe(dppe)3]2+ + 3 bipy |
 |
[Fe(bipy)3]2+ + 3 dppe |
|
[Solution] |
| 5. |
| KI + I2 |
 |
K+ + I3− |
|
[Solution] |
| 6. |
| Me3PBBr3 + Me3NBF3 |
 |
Me3PBF3 + Me3NBBr3 |
|
[Solution] |
| 7. |
| MeHgBr + HCl |
 |
MeHgCl + HBr |
|
[Solution] |
| 8. |
| AgCl2− + 2 CN− |
 |
Ag(CN)2− + 2 Cl− |
|
[Solution] |
| 9. |
| NaI + TlF |
 |
NaF + TlI |
|
[Solution] |
| 10. |
| HgS + ZnO |
 |
HgO + ZnS |
|
[Solution] |
| 11. |
| Cr(SCN)3 |
 |
Cr(NCS)3 |
|
[Solution] |
| 12. |
| [Mn(dppe)3]2+ + [Pd(en)3]2+ |
 |
[Mn(en)3]2+ + [Pd(dppe)3]2+ |
|
[Solution] |
| 13. |
| HF + I− |
 |
F− + HI |
|
[Solution] |
| 14. |
| LiBr + AuCl |
 |
LiCl + AuBr |
|
[Solution] |
| 15. |
| Mn(SH)43+ + 4 OH− |
 |
Mn(OH)43+ + 4 SH− |
|
[Solution] |
| 16. |
| Al(acac)3 + 3 dppe |
 |
[Al(dppe)3]3+ + 3 acac− |
|
[Solution] |
| 17. |
| F3BH− + BH3 |
 |
BH4− + BF3 |
|
[Solution] |
| 18. |
| Hg(OH)2 + Mn(SH)2 |
 |
Hg(SH)2 + Mn(OH)2 |
|
[Solution] |
| 19. |
| Cr(ox)3 + W6+ |
 |
Cr6+ + W(ox)3 |
|
[Solution] |
| 20. |
| Co(CN)64− + Co3+ |
 |
Co(CN)63− + Co2+ |
|
[Solution] |
| 21. |
| NaBr + LiCl |
 |
NaCl + LiBr |
|
[Solution] |
| 22. |
| Fe(acac)3 + Fe2+ |
 |
[Fe(acac)3]− + Fe3+ |
|
[Solution] |
| 23. |
| MgCO3 + Ca2+ |
 |
Mg2+ + CaCO3 |
|
[Solution] |
| 24. |
| Fe2O3 + 3 S2− |
 |
Fe2S3 + 3 O2− |
|
[Solution] |
| 25. |
| Me3P−BF3 + NMe3 |
 |
Me3N−BF3 + PMe3 |
|
[Solution] |
| 26. |
| Hg(NCS)2 |
 |
Hg(SCN)2 |
|
[Solution] |
| 27. |
| Ni(CO)4 |
 |
Ni(CO)42+ |
|
[Solution] |
| 28. |
| Au2O3 + 3 S2− |
 |
Au2S3 + 3 O2− |
|
[Solution] |
| 29. |
| MgF2 + CaBr2 |
 |
MgBr2 + CaF2 |
|
[Solution] |
| 30. |
| Ni(CO)4 + 4 H2O |
 |
Ni(H2O)4 + 4 CO |
|
[Solution] |
| | | |
| 1. |
Hg+ is a softer acid than Li+, I− is a softer base than F−
| HgI + LiF |
K < 1
 |
HgF + LiI |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 2. |
Tl+ is a softer acid than Na+, H− is a soft base
| TlH + Na+ |
K < 1
 |
Tl+ + NaH |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 3. |
Cu(0) is a soft acid, SOMe2 is a softer base than OSMe2
| Cu(SOMe2) |
K < 1
 |
Cu(OSMe2) |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 4. |
Fe2+ is a hard acid, bipy (N) is a harder base than dppe (P)
| [Fe(dppe)3]2+ + 3 bipy |
K > 1
 |
[Fe(bipy)3]2+ + 3 dppe |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 5. |
I2 is a softer acid than K+, I− is a soft base
| KI + I2 |
K > 1
 |
K+ + I3− |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 6. |
BBr3 is a softer acid than BF3, PMe3 is a softer base than NMe3
| Me3PBBr3 + Me3NBF3 |
K < 1
 |
Me3PBF3 + Me3NBBr3 |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 7. |
MeHg+ is a softer acid than H+, Br− is a softer base than Cl−
| MeHgBr + HCl |
K < 1
 |
MeHgCl + HBr |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 8. |
Ag+ is a soft acid, CN− is a softer base than Cl−
| AgCl2− + 2 CN− |
K > 1
 |
Ag(CN)2− + 2 Cl− |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 9. |
Tl+ is a softer acid than Na+, I− is a softer base than F−
| NaI + TlF |
K > 1
 |
NaF + TlI |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 10. |
Hg2+ is a softer acid than Zn2+, S2− is a softer base than 2−
| HgS + ZnO |
K < 1
 |
HgO + ZnS |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 11. |
Cr3+ is a hard acid, NCS− is a harder base than SCN−
| Cr(SCN)3 |
K > 1
 |
Cr(NCS)3 |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 12. |
Pd2+ is a softer acid than Mn2+, dppe (P) is a softer base than en (N)
| [Mn(dppe)3]2+ + [Pd(en)3]2+ |
K > 1
 |
[Mn(en)3]2+ + [Pd(dppe)3]2+ |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 13. |
H+ is a hard acid, F− is a harder acid than I−
| HF + I− |
K < 1
 |
F− + HI |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 14. |
Au+ is a softer acid than Li+, Br− is a softer base than Cl−
| LiBr + AuCl |
K > 1
 |
LiCl + AuBr |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 15. |
Mn7+ is a hard acid, OH− is a harder base than SH−
| Mn(SH)43+ + 4 OH− |
K > 1
 |
Mn(OH)43+ + 4 SH− |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 16. |
Al3+ is a hard acid, acac− (O) is a harder base than dppe (P)
| Al(acac)3 + 3 dppe |
K < 1
 |
[Al(dppe)3]3+ + 3 acac− |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 17. |
BH3 is a softer acid than BF3, H− is a soft base
| F3BH− + BH3 |
K > 1
 |
BH4− + BF3 |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 18. |
Hg2+ is a softer acid than Mn2+, SH− is a softer base than OH−
| Hg(OH)2 + Mn(SH)2 |
K > 1
 |
Hg(SH)2 + Mn(OH)2 |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 19. |
Cr6+ is a harder acid than W6+, ox2− is a hard base
| Cr(ox)3 + W6+ |
K < 1
 |
Cr6+ + W(ox)3 |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 20. |
Co2+ is a softer acid than Co3+, CN− is a soft base
| Co(CN)64− + Co3+ |
K < 1
 |
Co(CN)63− + Co2+ |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 21. |
Na+ is a softer acid than Li+, Br− is a softer base than Cl−
| NaBr + LiCl |
K < 1
 |
NaCl + LiBr |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 22. |
Fe3+ is a harder acid than Fe2+, acac− is a hard acid
| Fe(acac)3 + Fe2+ |
K < 1
 |
[Fe(acac)3]− + Fe3+ |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 23. |
Mg2+ is a harder acid than Ca2+, CO32− is a hard base
| MgCO3 + Ca2+ |
K < 1
 |
Mg2+ + CaCO3 |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 24. |
Fe3+ is a hard acid, O2− is a harder base than S2−
| Fe2O3 + 3 S2− |
K < 1
 |
Fe2S3 + 3 O2− |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 25. |
BF3 is a hard acid, NMe3 is a harder base than PMe3
| Me3P−BF3 + NMe3 |
K > 1
 |
Me3N−BF3 + PMe3 |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 26. |
Hg2+ is a soft acid, SCN− is a softer base than NCS−
| Hg(NCS)2 |
K > 1
 |
Hg(SCN)2 |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 27. |
Ni(0) is a softer acid than Ni2+, CO is a soft base
| Ni(CO)4 |
K < 1
 |
Ni(CO)42+ |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 28. |
Au3+ is a soft acid, S2− is a softer base than O2−
| Au2O3 + 3 S2− |
K > 1
 |
Au2S3 + 3 O2− |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 29. |
Ca2+ is a softer acid than Mg2+,
| MgF2 + CaBr2 |
K < 1
 |
MgBr2 + CaF2 |
|
[Back to Questions] |
| | | |
| | | |
| | | |
| 30. |
Ni(0) is a soft acid, CO is a softer base than H2O
| Ni(CO)4 + 4 H2O |
K < 1
 |
Ni(H2O)4 + 4 CO |
|
[Back to Questions] |
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